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Redox indicator
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A redox indicator (also called an oxidation-reduction indicator) is an indicator which undergoes a definite color change at a specific electrode potential.

The requirement for fast and reversible color change means that the oxidation-reduction equilibrium for an indicator needs to be established very quickly. Therefore, only a few classes of organic redox systems can be used for indicator purposes.

There are two common classes of redox indicators:

  • of and . In these systems, the metal changes oxidation state.
  • organic redox systems such as . In these systems, a proton participates in the redox reaction. Therefore, sometimes redox indicators are also divided into two general groups: independent or dependent on pH.

The most common redox indicator are organic compounds. Redox Indicator example: The molecule 2,2'- Bipyridine is a redox Indicator. In solution, it changes from light blue to red at an electrode potential of 0.97 V.


pH independent
RuIII/II(2,2'-bipyridine)3+1.33greenorange
Nitro (Fe complex)+1.25cyanred
N-Phenylanthranilic acid+1.08violet-redcolorless
1,10-Phenanthroline iron(II) sulfate complex ()+1.06cyanred
N-Ethoxychrysoidine+1.00redyellow
2,2`- (Fe complex)+0.97cyanred
5,6-Dimethyl (Fe complex)+0.97yellow-greencyan
+0.85redcolorless
Sodium diphenylamine sulfonate+0.84red-violetcolorless
Diphenylbenzidine+0.76violetcolorless
+0.76violetcolorless
-0.43colorlessblue


pH dependent
Sodium 2,6-Dibromophenol-indophenol or Sodium +0.64+0.22bluecolorless
Sodium o-Cresol +0.62+0.19bluecolorless
(syn. Lauth's violet)+0.56+0.06violetcolorless
+0.53+0.01HEWITT, LF. "Oxidation-Reduction Potentials in Bacteriology and Biochemistry." Oxidation-Reduction Potentials in Bacteriology and Biochemistry. Edn 6 (1950).bluecolorless
Indigotetra+0.37-0.05bluecolorless
Indigotri+0.33-0.08bluecolorless
(syn. Indigodi+0.29-0.13bluecolorless
+0.26-0.16bluecolorless
+0.28-0.25redcolorless
+0.24-0.29red-violetcolorless
+0.24-0.33redcolorless


See also


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